Research Catalog

Details

Description

1. xi, 444 pages : illustrations; 26 cm

Summary

1. This text highlights existing and developing technical applications of organic ion radicals; the formation and transformation of ion radicals in typical conditions of organic synthesis; and reviews organic ion radical reactions, especially when applicable to ecological and biological processes.

Subject

1. Radicals (Chemistry)
2. Ions
3. Organic compounds
4. Ions
5. Organic Chemicals
6. organic compounds
7. SCIENCE > Chemistry > Physical & Theoretical
8. Organische Verbindungen
9. Radikalion

Contents

1. Chapter 1. Nature of Organic Ion Radicals and Their Ground-State Electron Structure -- 1.1. Introduction -- 1.2. Unusual Features -- 1.3. Acid -- Base Properties of Organic Ion Radicals -- 1.4. Metallocomplex Ion Radicals -- 1.5. Organic Ion Radicals with Several Unpaired Electrons and/or Charges -- 1.6. Polymeric Ion Radicals -- 1.7. Inorganic Ion Radicals in Reactions with Organic Substrates -- 1.8. Conclusion -- Chapter 2. Formation of Organic Ion Radicals -- 2.1. Introduction -- 2.2. Chemical Methods of Organic Ion Radical Preparation -- 2.3. Equilibria in Liquid-Phase Electron-Transfer Reactions -- 2.4. Electrochemical Methods Versus Chemical Methods -- 2.5. Formation of Organic Ion Radicals in Living Organisms -- 2.6. Organic Ion Radicals in Solid Phases -- 2.7. Isotope-Containing Organic Compounds as Ion Radical Precursors -- 2.8. Conclusion -- Chapter 3.
2. Basic Principles of Organic Ion Radical Reactivity -- 3.1. Introduction -- 3.2. Principle of the "Detained" Electron That Controls Ion Radical Reactivity -- 3.3. Principle of the "Released" Electron That Controls Ion Radical Reactivity -- 3.4. Behavior of Organic Ion Radicals in Living Organisms -- 3.5. Conclusion -- Chapter 4. How to Discern Ion Radical Mechanisms of Organic Reactions -- 4.1. Introduction -- 4.2. Why Does a Reaction Choose the Ion Radical Mechanism? -- 4.3. Chemical Approaches to the Identification of Ion Radical Reactions -- 4.4. Physical Approaches to the Identification of Ion Radical Reactions -- 4.5. Examples of Complex Approaches to the Discernment of the Ion Radical Mechanism of Particular Reactions -- 4.6. Conclusion -- Chapter 5. How to Optimize Organic Ion Radical Reactions -- 5.1. Introduction -- 5.2. Physical Effects -- 5.3. Effect of Chemical Additives -- 5.4.
3. Solvent Role -- 5.5. Salt Effects.
4. 5.6. Conclusion -- Chapter 6. Organic Ion Radicals in Synthesis -- 6.1. Introduction -- 6.2. Reductive Reactions -- 6.3. Ion Radical Polymerization -- 6.4. Cyclization -- 6.5. Ring Opening -- 6.6. Fragmentation -- 6.7. Bond Formation -- 6.8. Conclusion -- Chapter 7. Practical Applications of Organic Ion Radicals -- 7.1. Introduction -- 7.2. Organic Ion Radicals in Optoelectronics -- 7.3. Organic Metals -- 7.4. Organic Magnets -- 7.5. Organic Lubricants -- 7.6. Ion Radical Routes to Lignin Treatment -- 7.7. Conclusion -- Chapter 8. Concluding Remarks -- 8.1. Introduction -- 8.2. S[subscript RN]1 Reaction -- 8.3. Stereochemical Aspects of Ion Radical Reactivity -- 8.4. Conclusion.

Owning institution

1. Princeton University Library

Bibliography (note)

1. Includes bibliographical references and indexes.